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What type of change occurs when a counterfeit pen?

Counterfeit pens are used to detect counterfeit banknotes and determine if they are genuine or fake. They work by detecting changes in ink on the banknote paper. When a counterfeit pen is used on legitimate currency, a chemical reaction occurs resulting in a color change of the ink. However, on counterfeit bills, the ink does not change color. This color change, or lack thereof, indicates whether the currency is real or fake. But what exactly is happening at the chemical level when a counterfeit pen is used? Let’s take a closer look at the science behind counterfeit pens.

How Counterfeit Pens Work

Counterfeit pens contain a special solvent ink that reacts differently to the inks used in legitimate currency compared to fake bills. The ink in real currency contains substances that are not found in common printer or copier inks. When the solvent in the counterfeit pen comes into contact with the ink on real bills, it causes a chemical reaction that results in a color change. However, with fake bills printed using regular ink, this chemical reaction does not occur, so the ink remains the same color.

The most common chemical used in counterfeit pens is an organic solvent called 1,2-dichloroethane. This clear, volatile liquid dissolves the ink components in genuine currency. Other chemicals such as phenylbenzene and o-toluidine may also be present in the pens. When these solvents interact with the ink printed on real paper money, it breaks down the ink pigments and dyes. This causes the color to change. The most common color change is from yellow or pale brown to black or dark brown when a real bill is tested.

Ink Components in Real vs. Fake Currency

The key difference between real banknotes and counterfeits lies in the ink composition. The ink on genuine bills contains unique chemicals and pigments that are very hard to duplicate.

Some of the typical components found in real currency ink include:

  • Ethyl violet – a violet dye
  • Phenylmethyl benzoate – an odorless compound used as a solvent
  • Benzyl phenyl acetate – used as a solvent for inks and coatings
  • Chromophtal yellow – an organic pigment
  • Toluidine red – a reddish synthetic azo dye

These chemicals are mixed with binders, waxes, and other agents to create an ink that has unique chemical properties. Even the paper used for real currency has specialized sizing and coatings to interact with the ink.

In contrast, counterfeit currency is often printed with standard inkjet or toner inks that lack these specialized chemicals. These everyday inks do not contain reagents that react with the solvent in counterfeit pens.

The Chemical Reaction

When the organic solvents in a counterfeit pen make contact with the ink on real currency, it causes the dyes and pigments to break down and spread. Some common chemical changes include:

  • The phenylmethyl benzoate solvent disperses the ink pigments, causing them to loosen and appear darker.
  • Ethyl violet dye molecules detach and dissolve, increasing the visible color.
  • Binder polymers dissolve, spreading the ink.
  • Printed lines and edges blur as ink components diffuse.

For pens that use 1,2-dichloroethane as the main solvent, the following reaction occurs:

1,2-dichloroethane + ink components → color change to black/dark brown

The dissolving ink pigments, combined with the spreading and blurring, cause the overall ink color to turn darker. With real currency, a clear, distinctive color change is observed. But on fake bills, without those specialized chemicals, the everyday printer inks remain unchanged.

Factors that Influence the Reaction

Several factors can affect the visibility and intensity of the color change on legitimate banknotes:

  • Ink age – Older ink that has faded may not show as intense a reaction.
  • Ink location – Areas with denser printed ink react more.
  • Solvent chemistry – Pens use different solvents which can vary the reaction.
  • Paper quality – The sizing and coatings on real bills influence ink behavior.
  • Temperature – Colder temperatures slow the reaction time.

Using the pen correctly is also important. Lightly brushing across the bill allows time for the solvent to dissolve the ink. Too much rubbing or scrubbing can mechanically smear the ink rather than chemically changing it. Properly filling and priming the pen ensures sufficient solvent volume.

Under optimal conditions with fresh ink and solvent, the color change on authentic currency should be distinct and unmistakable. This ensures the pen is an effective method for detecting counterfeits printed with mismatched inks.

Conclusion

Counterfeit pens provide a simple, fast way to screen suspicious banknotes and determine if they may be fake. This is accomplished by detecting the chemical changes that occur when the pen ink interacts with the specialized ink on real currency. While the exact mechanisms are complex, the basic process involves organic solvents dissolving dye pigments and blurring printed lines of legitimate ink. This creates an obvious color change. Without those same ink components, counterfeits stay the same. Understanding this chemical reaction allows users to have confidence in the results of their counterfeit pen.

Ink Component Found in Real Currency Found in Counterfeits
Ethyl violet dye Yes No
Phenylmethyl benzoate Yes No
Chromophtal yellow pigment Yes No
Toluidine red dye Yes No
Common inkjet/toner inks No Yes

This table summarizes the key differences between the ink components found in real vs. counterfeit currency that lead to the chemical reaction seen with counterfeit pens.